Ibuprofen elimination from water and wastewater using sonication/ultraviolet/hydrogen peroxide/zeolite-titanate photocatalyst system

Ramavandi, B and Tabatabaie, T and Farhadi, N and Amiri, F (2021) Ibuprofen elimination from water and wastewater using sonication/ultraviolet/hydrogen peroxide/zeolite-titanate photocatalyst system. Environmental Research, 198. ISSN 00139351

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Abstract

The present investigation was designed to remove ibuprofen from aqueous solutions and wastewater by activating hydrogen peroxide using ultrasonication (US)/ultraviolet (UV) radiation/zeolite-titanium. The physical-chemical properties of the photocatalyst were determined using BET, FTIR, XRD, FESEM, and EDX-mapping techniques. The titanium oxide crystal size and the catalyst BET were determined to be 4.97 nm and 39.88 m2/g, respectively. Tests were performed in a reactor (with a volume of 316 mL) located in an ultrasonic bath to intensify reactions. The synergistic impact of the components of the UV/US/H2O2/Photocatalyst system was explored. The maximum efficiency (99.58%) was obtained at H2O2 concentration of 0.05 mM, pH 5, UV power of 6 W, photo-catalyst dose of 1 g/L, and contact time of 100 min. The pH variable was more effective than the other parameters. Ions of NO3−, Cl−, and SO42− had a slightly negative effect on contaminant removal efficiency. The ibuprofen removal (based on COD) from urban water and hospital wastewater was attained 77.82% and 66.24%, respectively. The ibuprofen removal by the developed system followed the first-order kinetic. The results show that the system has high efficiency and reasonable costs (with treatment cost of 6.25 €/m3) for ibuprofen decontamination.

Item Type: Article
Subjects: T Technology > TD Environmental technology. Sanitary engineering
Divisions: Faculty of Engineering, Science and Mathematics > School of Chemistry
Depositing User: خدیجه شبانکاره
Date Deposited: 28 Jun 2021 05:50
Last Modified: 28 Jun 2021 05:50
URI: http://eprints.bpums.ac.ir/id/eprint/9284

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